Cobalt

Cobalt is a chemical element with symbol Co and atomic number 27. Like nickel, cobalt is found in the Earth’s crust only in chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, produced by reductive smelting, is a hard, lustrous, silver-gray metal.

Cobalt-based blue pigments (cobalt blue) have been used since ancient times for jewelry and paints, and to impart a distinctive blue tint to glass, but the color was later thought by alchemists to be due to the known metal bismuth. Miners had long used the name kobold ore (German for goblin ore) for some of the blue-pigment producing minerals; they were so named because they were poor in known metals, and gave poisonous arsenic-containing fumes upon smelting. In 1735, such ores were found to be reducible to a new metal (the first discovered since ancient times), and this was ultimately named for the kobold.

Today, some cobalt is produced specifically from various metallic-lustered ores, for example cobaltite (CoAsS), but the main source of the element is as a by-product of copper and nickel mining. The copper belt in the Democratic Republic of the Congo, Central African Republic and Zambia yields most of the cobalt mined worldwide.

Cobalt is primarily used in the preparation of magnetic, wear-resistant and high-strength alloys. The compounds, cobalt silicate and cobalt(II) aluminate (CoAl2O4, cobalt blue) give a distinctive deep blue color to glass, ceramics, inks, paints and varnishes. Cobalt occurs naturally as only one stable isotope, cobalt-59. Cobalt-60 is a commercially important radioisotope, used as a radioactive tracer and for the production of high energy gamma rays.

Cobalt is the active center of coenzymes called cobalamins, the most common example of which is vitamin B12. As such, it is an essential trace dietary mineral for all animals. Cobalt in inorganic form is also micronutrient for bacteria, algae and fungi.

Cobalt is a ferromagnetic metal with a specific gravity of 8.9. The Curie temperature is 1,115 °C (2,039 °F)[3] and the magnetic moment is 1.6–1.7 Bohr magnetons per atom.[4] Cobalt has a relative permeability two-thirds that of iron.[5] Metallic cobalt occurs as two crystallographic structures: hcp and fcc. The ideal transition temperature between the hcp and fcc structures is 450 °C (842 °F), but in practice, the energy difference is so small that random intergrowth of the two is common.[6][7][8]

Cobalt is a weakly reducing metal that in pure metallic form, is protected from oxidation by a passivating oxide film. It is attacked by halogens and sulfur. Heating in oxygen produces Co3O4 which loses oxygen at 900 °C (1,650 °F) to give the monoxide CoO.[9] The metal reacts with fluorine (F2) at 520 K to give CoF3; with chlorine (Cl2), bromine (Br2) and iodine (I2), producing equivalent binary halides. It does not react with hydrogen gas (H2) or nitrogen gas (N2) even when heated, but it does react with boron, carbon, phosphorus, arsenic and sulfur.[10] At ordinary temperatures, it reacts slowly with mineral acids, and very slowly with moist, but not with dry, air.